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The carefully cultivated hills south of Siena culminate in Tuscany’s highest peak, the extinct volcano Monte Amiata (1,738 metres). Fortified villages crown the hilltops: most enticing is timeless little Montalcino, famed for its Brunello wines and 14th-century fortress. San Quirico d’Orcia’s showpiece is its Collegiata church with Romanesque portals. Pienza, remodelled by Pope Pius II, is a perfectly preserved Renaissance city.